I published the article below showing the pectorals can push the arm across as well as pull it toward the chest (Abduct and Adduct).
Article The Role of Compressive Force in the Movement of the Pectoralis Major
I used the same explanation for the diaphragm, but the reviewers seem skeptical that the chest expands when breathing. I know of no conventional explanation for why this happens. But it is easily varifiable, I wasn't expecting push back for that fact.
Deleted research item The research item mentioned here has been deleted