Can I use palladium chloride instead of palladium acetate for buchwald hartwig amination?

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Samuel Kuranchie Akompong

To the best of my knowledge, both can be used. However, due to Pd(OAc)2 being more soluble in organic solvents, it is crucial to check the solvent in use, as well as other reaction conditions such as temperature and the choice of base

Amrita Pathak

Samuel Kuranchie Akompong thank you so much for the help. I'm using anhydrous toluene as a solvent. I'll check the solubility of palladium chloride before starting my reaction.

Philippe Roger Bovy

There are published cases where PdCl2 is used, see

Buchwald-Hartwig Cross Coupling Reaction (organic-chemistry.org)

Gregory Arzoumanidis

A good alternative is Pd(CF3COO)2. Should be more effeicient than palladium acetate.