What is special about decomposition products and additives of a cellulose-based electrode that helps an electric arc during welding to be less spread out? What would be a feasible mechanism linking this phenomena with decomposition product and plasma column composition during arc welding? Typical welding handbooks and references merely state the phenomena (i.e. punchy arc by H2/CO) without explaining the mechanism behind (e.g. what chemical characteristic of these two gases provide the "punch" and penetration of arc).
In general, what are the mode of action of chemical additives of an welding arc that modifies its welding penetration characteristics?