The more sensivitive polymers towards UV ageing are polymers for which the structural units absorb in the UV range (generally from 300 to 330 nm). You can find all the polymers containing aromatic rings as PS, PC and PET. If you use commercial polymers, do not forget to verify if these polymers have not previously stabilized by incorporating of stabilizing agents.
Try any polymer with a tertiary carbon atom in the backbone, such as PP or use a polymer with high levels of unsaturation or aromatic groups in the backbone, such as aramids.
any polymer have an azobenzene as copolymer in its struture will have a very low UV-resistant , becuase the azobenzene have high UV absorbance. Under UV irradiation, its struture will change from cis to trans