Thank you for reply, but what about the paper titled "Metallic hole conduction in CuS", Journal of Solid State Chemistry
Volume 91, Issue 2, April 1991, Pages 306-311, they found that "The source of the hole carriers is discussed based on Hall effect data and structural considerations. It is concluded that conduction is due to holes in a valence band which is mainly constituted from the 3p orbitals of sulfur."