Good to see you used different calibration standards!
Please review my reply to your earlier question. Yes, it is possible and expected. The pH-scale pH = -log [H3O+], so if your proton concentration is 2.5 moles/liter your pH = - log(2.5) = - 0.40.
If you have not seen it yet, this article from the Journal of Chemical Education might interest you. It is open-access from the publisher and has been viewed almost 30000 times: DOI: 10.1021/ed083p1465.