Sorry, I'm not providing an answer. I just want to say that partial oxidation or combustion with a great deficiency in oxygen is a "grey area" for even simple cases such as partial oxidation of methane into syngas without a catalyst.
As for as I know, the gasification is not included in the Fluent. Note that the gasification relates strongly to the the combustion mechanisms. It's not reasonable to include a model in CFD without the mechanisms. If you really need to do so, you should find the mechanism you need and import it in your Fluent model.