I'm certainly no expert when it comes to spin coating, as for thin film work we find PVD a better alternative, but as you are working on TiO2, I've had a look for you. (I used to work on Ti4O7 and Ti5O9 - the Magnelli phases.) Here is a paper I've found that suggests you may be able to achieve this with an alcohol based solution:
If you insist on spin coating, the most easiest way to deposit TiO2 is to use a Ti-alkoxide such as titanium isopropoxide (Ti[OC3H7]4, provided e.g. by Sigma Aldrich), and use it in a spin coater. The metal-organic compound will be hydrolyzed by the humidity in air, this way transforming into the oxide. Without a heat treatment, those films are usually amorphous, but depending on the annealing temperature and time, rutile as well a anatase phases may be generated!