Hi, I have never actually measured the pressure, but i can assure you that you will usually not need very low pressures. Check the following link: http://blogs.rsc.org/chipsandtips/2013/10/02/periodic-degassing-of-pdms-to-create-a-perfect-bubble-free-sample/
For degassing the PDMS, it's also important to use the shutter of the desicator to allow some air in during the process, which will cause many large bubbles on the surface to explode. So low level or vacuum is only one factor.
By the way, PDMS is much easier than some of the resins in terms of degassing, because latter only allow you