There are a few methods to determine the purity of TiCl4, such as the Cryoscopic Measurement of Purity. This method is explained in detail in the following link where you find some useful information too that can be helpful for your studies.
Actually, TiCl4 is very sensitive to water and if you need advice regarding the purity, you should follow the specification information in sigma-Aldrich.
At the same time, can you tell me what are you needing in this material?