Dear Dr Debabrata Nath . They relate to each other directly. lower soil pH indicates larger number of hydrogen ions in the soil. Hydrogen ions can appear in varying amount in the soil environment which can affect the level of electrical conductivity.. See the following RG link: https://www.researchgate.net/figure/Relationship-between-Soil-pH-and-Soil-ECdS-m_fig3_286451967
Kindly check also the following useful link: https://www.citefactor.org/journal/pdf/Soil-pH-and-Electrical-Conductivity-A-Case-Study-of-Damaturu-Northeast-Nigeria.pdf
Soil pH affects all the physical, biological and chemical soil properties and the growth of specific organisms, soil microbial biomass, and microbial activity. The pH of a soil is a measure of the active acidity, that portion of hydrogen ions that is active in soil solution where the negative logarithm of hydrogen concentration is used as an indicator and is measured in pH units. The EC is a measurement of dissolved materials in aqueous solution which relates to the ability of the material to conduct electrical current through it. However, Soil PH has a negative relationship with soil electrical conductivity.