Can anyone please explain what is the difference between self diffusion coefficient and the diffusion coefficient? What is the mathematical relationship between these? Also suggest me some book or material to read to gain clarity on this
The diffusion coefficient is the dimensionful constant that appears in the diffusion equation. Any book on stochastic processes describes this material; one example would be ``Stochastic processes in physics and chemistry'' by van Kampen.
Diffusion coefficient is the rate of diffusion equal to the amount of substance (in mass units) passing per unit time through a section of unit area (for example, 1 m2) as a result of the thermal movement of molecules with a concentration gradient equal to unity.
Self-diffusion, a special case of diffusion in a pure substance or solution of constant composition, in which the substance’s own particles diffuse. The atoms (molecules) involved in self-diffusion have the same chemical properties, but may differ in molecular weight.
Uphill diffusion see https://www.researchgate.net/post/Difference_between_self_diffusivity_and_diffusion_coefficient?isAnswerFieldFocused=true