I was wondering if it is possible to add a second photoinitiator to SU-8 to photopolymerize it at higher wavelengths. Theoretically, it seems doable, but I'm unsure about the chemistry~
This is certainly possible (anything is possible). SU-8 is an acid catalyzed photoresist, meaning the photo acid generator (PAG) produces a proton (acid) upon absorption of a photon. Then the proton diffuses around and facilitates the polymerization reaction of the epoxy groups. One product of this chemical reaction is a proton, which can facilitate further reactions. That's why it's called catalyzed reaction. Seems you are looking for a near IR PAG. Assuming 1um wavelength, this would be a photon energy of 1.2eV. This is still very doable at room temperature without risk of thermally activated reaction. You want to find a PAG which produces the proton at the wavelength of your desire. I am not an expert here and cannot help finding such a chemical. Good luck!