Actually, I think may be it is difficult to accurately obtain such a thin MgO layer using thermal evaporation. You may need to try a lot to achieve high accuracy. I would suggest you to use the atomic layer deposition (ALD). As indicated by its name, the deposition rate is very low in ALD since the film is grown in the way of atom layer by atomic layer.
I doubt you can prepare MgO by thermal evaporation. You need to use e-beam evaporation in order to evaporarte the material with such high boiling point.