as already mentioned nanodrop measures sample purity but not RNA integrity. In the context of your plant material I surmise that phenolic compounds that require specialist removal; are not specifically detected by 260/280 or 260/230; and if contaminating your final DNA prep will degrade your genomic DNA. Removal of phenolic residues with CTAB, PVDF or boric acid will possibly prevent degradation. In particular
260/280 ratios of >1.7 imply minimal contamination with proteins and especially RNAses
260/230 ratios > 1.0 imply minimal contamination with salts and especially GITC designed to provide a stable extraction environment by inhibiting RNAses
Thus the usual candidates for degradation are probably not responsible
In Contrast phenolic compounds replete in plants paradoxically increase 260/280 suggesting nothing untoward but in fact mask a contaminant that can degrade DNA and RNA
Indeed sometimes in the context of plant materials when 260/280 ratio is > 2.0 it sometimes suggests the presence of these compounds
To remove these compounds perform a CTAB extraction before conventional trizol and chloroform followed by isopropanol precipitation and 70% ethanol wash which remove protein lipids and GITC respectively