On another question I was told, twice, I should not prepare my phosphate buffer by titrating dihydrogen phosphate to pH 7 or 8. I don't see any problem, because the phosphate will dissociate in accordance to the pH, so there should be no difference between adding hydrogen phosphate and dihydrogen phosphate or titrating dihydrogen phosphate by KOH.

https://www.researchgate.net/post/Purification_on_hydroxyapatite2

What's your opinion?

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