I'm plating copper with nickel (electroless). Then, I'm doing porosity test according to the procedure below. I can't find the exact reactions going on between the ferrocyanide and the copper electrode beneath the nickel plating.
I've found a reaction with copper ions, but I don't understand how it reacts with solid copper (or how copper ions are formed).
2Cu+2(aq)+[Fe(CN)6]4−(aq)↽−−⇀Cu2[Fe(CN)6](s)
thank you in advance!
Porosity test procedure: