Bi-product along with methanol can be carbon monoxide, formaldehyde, formic acid and methane
As stated already, GC is method of choice for determination of MeOH. Please find application examples below:
http://www.sigmaaldrich.com/catalog/analytical/supelco/g005769
http://www.sigmaaldrich.com/catalog/analytical/supelco/7960685
I recommend you to use GC .It is much reliable for VOC.
GC technique on DB-624 column
Methanol is basically invisible in the UV (UV cutoff is ~205 nm) so the best method of analysis is GC.
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