You can use FAO reference, According FAO agricultural department, the rocommended maximum concentration of Cu and Cr are 0.20 and 0.10 mg/l. Moreover the link will be helpful for you! You can see this at table 4. Thanks.
To complete the good references already provided, you could find some data on typical Cu and Cr concentrations in industrial effluents in the EC BAT document on large volume inorganic chemicals at http://eippcb.jrc.ec.europa.eu/reference/BREF/lvic-s_bref_0907.pdf
There are certain regulations which says about the permissible limit of chromium such as EPA, FAO, WHO in soil and water. For wastewater from industry before it discharged to the environment the chromium must be reduced to the level of 0.5 mg/L (EPA). similarly, in drinking water the amount of chromium should be less than 0.05mg/L. Several papers are also there which discusses about this.
Cu should be 3 ppm if discharged as public sewer and surface water.Chromium as total should be 2ppm in both condition.We consider both in industrial effluent