You can do XRD to gain information about the crystallinity and phase purity of the synthesized MOF. Further through SEM, morphology and particle size distribution of the MOF crystals can be investigated.
Dear Ma'am Nildhara Parsana the same strategy mentioned by you is applicable for nanomaterials/ nanostructures, then what will be the difference between MOF and Nanomaterials in terms of characterisations? I mean like there must an appropriate preliminary technique before going for such expensive characterisations to confirm the synthesis of MOF.