Solubility of elementary sulfur in solvents?

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Isam Eldin Hussein Elgailani

Dear Sir. Concerning your issue about the solubility of elementary sulfur in DMSO as a function of temperature . The solubility of S in DMSO with 1 M of different salts was determined. First, in a pure organic solvent, the solubility of S is dependent on the polarity and the Lewis basicity of the solvent. The solubility of a non-polar S molecule should be higher in a non-polar solvent than that in a polar solvent, for example, the solubility of S in hexane is an order of magnitude higher than that in acetonitrile. I think the following below links may help you in your analysis:

https://pdfs.semanticscholar.org/a82f/3d5b321f7414e647b3db8ec93658c51b7b3c.pdf

http://publications.lib.chalmers.se/records/fulltext/251082/local_251082.pdf

http://web.gps.caltech.edu/~vijay/Papers/Chemistry/Meyer-76.pdf

Thanks

Carlos Araújo Queiroz

You may want to check 'TABLE VII' ('Solubility of miscellaneous materials in DMSO') at the technical document entitled 'Technical Bulletin ― Reaction solvent― Dimethyl sulfoxide (DMSO)', issued by Gaylord Chemical Corp.:

http://chemistry-chemists.com/N3_2011/U/DMSO-technical_bulletin.pdf

Rashid Nadirov

Dear Carlos Araújo Queiroz,

thank you for your kindly help.