For creating J-aggregation of cyanine dyes such as pseudoisocyanine dye by Langmuir-Blodgett trough, which one in better?

1: dissolving this dye and Arachidic acid in chloroform/methanol mixture, and       spreading this solution on the water

or

2: dissolving this dye in the water of the trough and spreading Arachidic               acid/chloroform solution on the water surface

?

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