I was thinking the same at first but I download the library and I haven't find the fontion polar.ord in its documentation, so I think it has been remove from the package. May be you can try to contact the author of "asbio" or try to find an older version of it and hope it still work with your actual R version. If not, you may try to install an older version of R for this special purpose.
I have written a custom command to carry out Polar Ordination. Check it out here: http://www.dataanalytics.org.uk/Publications/CERE%20Support/news.htm
You can download the .R file and use as you like. There are print, summary and plot methods. I am just updating my website to include some demonstration examples, which should be on-site quite soon.