If i not study effect of pH what is problem in this case?
I think you may find the response to your inquiry in the following papers:
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Article A novel voltammetric sensor for sensitive detection of mercu...
Article Anodic stripping voltammetry of lead and cadmium using a mer...
Article Mercury-free sono-electroanalytical detection of lead in hum...
If you used a strong acid as a supporting electrolyte for your electrochemical study, then the pH is the -log (H+). So, measuring individual pH is not necessary for your case.
Good luck
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