I have seen examples with singlet systems but I do not know if ORCA is able to do it with quintet complexes, or if I need to set some extra keyword.
You could take a look at this:
https://www.orcasoftware.de/tutorials/spec/SOC.html
Check out this manual
https://cec.mpg.de/fileadmin/media/Forschung/ORCA/orca_manual_4_0_1.pdf
Also check the supporting info of these two papers:
Article Challenges in Multireference Perturbation Theory for the Cal...
Article Ligand Field Theory and Angular Overlap Model Based Analysis...
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