Dear Reshma Kuppili You have to try different concentration at particular site for example barium site or titanium site. Some may form a structure and some may not.

Thank you Nitin Kumar for your answer.

I think you can do, EDX on multiple locations and compare the at%/mol%/wt% of doped atom with that of theoretical one. You may not get an exact amount, but you get a range...

Thank you Abhinay Sreeram and @Vaidehi Deshmukh for your input!

if your doping concentration is high (max

Thankyou Raju Mula for your input

Reshma Kuppili, you can perform ICP-OES/ICP-AES/ICP-MS to get the exact composition of each element in your material. Else, you can perform Rietveld analysis using Fullprof software to get the exact composition.

Thank you Siddhartha Nanda for your input.