Yes, you are right. Glycosaminoglycans (GAGs) are highly negatively charged because of sulfate or carboxyl groups on most of their sugars. Their highly negative charge attracts osmotically active cations like sodium ions, which causes large amounts of water to be incorporated into the matrix. This results in porous hydrated gels and is responsible for the turgor that enables the matrix to withstand compressive force.
Figure 1 of the following article will help you understand the hygroscopic properties of hyaluronan:
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Some references that include the relationship between sulfation, Na+ and PG hydration are abstracted here: https://www.sciencedirect.com/topics/medicine-and-dentistry/proteoglycan
The modeling for PG, hydration and compression resistance I am familiar with is in cartilage:
I am working with glycosaminoglycans (GAGs) (heteropolysaccharides) from a fish sample, and I am trying to dissolve the crude GAGs (extracted sample) with autoclaved distilled water, but the crude gags did not dissolve properly. Can anyone give me suggestions regarding this?