I working on the synthesis of Lanthanum Nitride(LaN). I have Lanthanum oxide as the precursor which is hygroscopic in nature. Please suggest some methods for the synthesis of LaN.
A wet-chemical synthesis (in water solutions) of nitrides of rare earths is absolutely not possible. Only thermochemical formation of nitrides of the rare earths would be possible, but not from oxides but from metals or other compounds (hydrides, halides and others). Because rare earth oxides are thermodynamically more stable than nitrides, a direct oxide-nitride transformation is not possible.
Start from metallic lanthanides or halides or some organic salt. It is very difficult to prepare nitride, phosphide or chalcogenides from the corresponding oxide, as rare-earth sesquioxides are very stable at ambient due to high reactivity with oxygen.