For specifying of sulfuric acid, in this situation, you have to use nondestructif methods: electroconductivity and resistivity; dielectrical transmissivity. What is plaster size and amount? Is the product continous or discontinous? If this is a waste from fertilizer factory by product, their acit ratio is bigger...If there isn't a problem for destructive analysis, you can try in the pyrolytic conditions like 900-1250 deg.C for a few hours in a furnace. Acids and water can fully removing from plaster. Remained solid is directly anhydrous gypsum.