Dose the metals oxides like (Fe3O4, ZnO TiO2) can coordinate with organic linker in the purpose of MOFs synthesis?
Dear Basem Keshta I'm certainly not an expert in this, but my guess is that the answer is NO. Metal oxides like Fe3O4, ZnO, TiO2 are insoluble solids, at least under normal conditions. You could of course try a hydrothermal synthesis of Fe3O4 or ZnO with suitable organic acids such as terephthalic acid. What is more common is the other way round, i.e. the synthesis of porous transition metal oxides from MOFs. See e.g. the following references which are available as public full texts on RG:
Metal and metal oxide nanoparticle synthesis from metal organic frameworks (MOFs): Finding the border of metal and metal oxides
Article Metal and metal oxide nanoparticle synthesis from metal orga...
Metal–Organic Framework (MOF)–Derived Metal Oxides for Supercapacitors
Chapter Metal–Organic Framework (MOF)–Derived Metal Oxides for Supercapacitors
Firstly Thank you, Mr Frank, for your answer that helps to clear my vision now. Frank T. Edelmann
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