Recently, we were trying to synthesize stannous-surfactant based catalyst for our polymerization process. The method it self was simple, by mixing SnCl2 dihydrate solution with surfactant solution until we obtained the precipitate according to literature. Previously we attempted to synthesize it with distilled water as solvent but the result obtained was unsatisfactory. Then we re-attempted the synthesize using ethanol 96% as solvent, but the EDX result showed strong deviation from our theoritical calculations. What could went wrong ? Should we change the metal, surfactant, or solvent ?
The deviation in EDX results when synthesizing the stannous-surfactant catalyst using ethanol may stem from solvent purity, stoichiometry, or surfactant compatibility. Ensure complete precipitation and proper EDX calibration to improve accuracy. If issues persist, consider trying different metal precursors, surfactants, or solvents to enhance synthesis outcomes.
Bayu Yusuf
We have obtained and studied such salts. They are obtained better in water. The main contribution to obtaining such salts is made by hydrophobic interaction, i.e. interaction mediated by water.
Your problem is poor determination of tin content by the EDХ method. In this method, organic molecules are decomposed by high electron energy. It is advisable for you to replace the analysis with a chemical method for determining tin, for example, spectrophotometric.
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