20 January 2016 5 5K Report

I am trying to find out what options there are for tensile-strained *optical films* as deposited by magnetron sputtering or, preferably, ion-beam sputter deposition.

It seems all oxides are compressively-strained, be it SiO, TaO, TiO, NbO, AlO etc.  Our nitrides are also compressive.  To deposit a thick multi-layer stack without delamination/cracking, I need to find a tensile-strained film to reduce the total film stress.  

Even Fluorinated dielectrics would be acceptable, or Selenides etc.  Has anyone encountered any tensile film at all deposited by sputtering?

The tools I'm currently looking to use are these:

http://signupmonkey.ece.ucsb.edu/wiki/index.php/Sputter_3_(AJA_ATC_2000-F)

Small magnetron targets for this tool shouldn't be too difficult to have fabricated.

http://signupmonkey.ece.ucsb.edu/wiki/index.php/Ion_Beam_Deposition_(Veeco_NEXUS)

The metal targets for this tool are large (~18inches), so could be difficult to obtain for uncommon metals.  

Both tools have gas lines for various process gasses - both have Ar/Xe for sputtering and O2/N2 for oxidation/nitridation, but I'm open to ideas that involve other process gasses.

(I know that ion-beam assisted electron-beam evaporation is a common way to achieve such films, we just don't have that available right now.)

Thanks in advance for taking the time to think about this.

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