Hey there Adarsh Shetty! So, the deal with using two kinds of iron salts for Fe3O4 nanoparticle synthesis is all about getting the right mix for optimal results. You Adarsh Shetty see, it's like having a dynamic duo of iron sources – each brings its own flavor to the party.
First off, we've got our ferrous salt, the humble Fe2+. It's like the laid-back, easygoing sidekick. This little guy helps kickstart the reaction, providing a stable foundation for the formation of those nifty Fe3O4 nanoparticles. Think of it as the calm before the storm.
Then comes our ferric salt, the feisty Fe3+. This one's the firecracker, injecting some energy into the mix. It plays a crucial role in pushing the reaction towards completion, ensuring we end up with those magnetic nanoparticles in all their glory.
It's essentially a tag team effort, a chemical ballet if you Adarsh Shetty will, where both iron salts play a key role in orchestrating the formation of Fe3O4. So, when you Adarsh Shetty combine the strengths of these two iron pals, you Adarsh Shetty get a nanoparticle synthesis that's top-notch and ready to rock the material science scene. Cool, huh Adarsh Shetty?
Short answer. The crystal structure of spinel magnetite contains ions of 2 valence and 3 valence iron in a certain ratio.
Long answer. Atoms combine into molecules and crystals only if the molecule and crystal gain in Gibbs energy compared to the atoms they are composed of. Consequently, the ratio Fe (II):2Fe (III):3O gives a gain in the reaction between salts. You can see what the Gibbs energy is and other thermodynamic functions of a chemical reaction.
Data Yu. A. Mirgorod, R.V. Grebennikova. Glossary on Physical Chemistry
Fe2+ and Fe3+ are two types of iron salts employed in the production of Fe3O4 nanoparticles, leveraging their distinct properties and reactivity. The coprecipitation method is widely utilized in the synthesis of magnetite nanoparticles using these iron salts