When you pyrolyze tires, you will get three products:
1) Gases that contain CH4, H2, CO, CO2, H2S, SO2, and other hydrocarbons. This gaseous mixture could be used for heating purpose and, hence, is a gorgeous fuel product..
2) Char. This could be another solid product.
3) Tar oil which is a liquid product that could be used as a fuel, in pharmaceuticals, etc.