Sorry...it is a coating process where only the surface in the direct view is coated (90 degrees +/- 5). It is the case of thermal spray processes where guns are used, or in the case of PVD where the condensed vapor is focalised on the surface. Thus internal diameters, corners and any other hard-to-reach surfaces remain uncoated. Hope it is clear
Physical vapour deposition techniques particularly thermal evaporation techniqus have fractionation effect, i.e., the composition of the alloy or compound may not remain same. CVD processes are relatively better for getting required concentration of constituent elements. However, if film of single element is required, PVD techniques can safely be used and are relatively easy as compared to CVD techniques.