13 September 2017 1 673 Report

I am currently utilising Raman spectroscopy for the first time, and am struggling to identify some peaks.

I understand that Raman peaks are due to the inelastic scattering of light, whose wavelength corresponds to the vibrational/rotational modes of the sample, and by comparing my shifts to the references reported elsewhere, I am able to identify my material.

One thing I am struggling to understand, however, is the reasons behind shift locations, what causes it? Whats an acceptable shift? and what determines peak breadth? 

If anyone could help me with these issues, I would appreciate it greatly.

Best wishes

Jamie

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