Sometimes porosity is confused with the pore size (which is wrong). With correct definition of porosity (as a volume fraction of void space) there may be an indirect dependence of rejection on it due to the dependence of extent of concentration polarization on the volume flux. At higher porosity the flux will be larger and rejection lower.
Thanks for your time and information. We have two kinds of porosity: surface porosity and total porosity. My question was about the second one. Maybe the sentence which I saw was about surface porosity!