Can I use RAMAN spectroscopy for discriminate between organic and inorganic phosphorus forms in soil samples?
Dear Bruno M. Chavez-Vergara,
The reaction mechanisms of phosphate-bearing mineral phases from sewage sludge ash-based fertilizers in soil were determined by Raman and synchrotron infrared microspectroscopy. Different reaction mechanisms in wet soil were found for calcium and magnesium (pyro-) phosphates. Calcium orthophosphates were converted over time to hydroxyapatite. Conversely, different magnesium phosphates were transformed to trimagnesium phosphate. Since the magnesium phosphates are unable to form an apatite structure, the plant-available phosphorus remains in the soil, leading to better growth results observed in agricultural pot experiments. The pyrophosphates also reacted very differently. Calcium pyrophosphate is unreactive in soil. In contrast, magnesium pyrophosphate quickly formed plant-available dimagnesium phosphate.Also the chemical form of phosphate phases in sewage sludge ash (SSA)-based fertilizers was determined by Raman microspectroscopy. Raman mapping with a lateral resolution of 5 × 5 μm(2) easily detected different compounds present in the fertilizers with the help of recorded reference spectra of pure substances. Phosphates with apatite structure and magnesium triphosphate were determined at around 960 and 980 cm(-1), respectively. Furthermore, calcium/magnesium pyrophosphates were detected in some samples. The review comprises the analysis of natural matrixes by IR, XRF or Raman and chemometrics. Potential applications of non-destructive spectroscopic techniques to achieve these principles are discussed in this review. Special emphasis is placed in environmental samples.
Regards,
Prem Baboo
Article Determination of Phosphorus Fertilizer Soil Reactions by Ram...
Article Determination of Phosphate Phases in Sewage Sludge Ash-Based...
Dear Bruno M. Chavez-Vergara,
The reaction mechanisms of phosphate-bearing mineral phases from sewage sludge ash-based fertilizers in soil were determined by Raman and synchrotron infrared microspectroscopy. Different reaction mechanisms in wet soil were found for calcium and magnesium (pyro-) phosphates. Calcium orthophosphates were converted over time to hydroxyapatite. Conversely, different magnesium phosphates were transformed to trimagnesium phosphate. Since the magnesium phosphates are unable to form an apatite structure, the plant-available phosphorus remains in the soil, leading to better growth results observed in agricultural pot experiments. The pyrophosphates also reacted very differently. Calcium pyrophosphate is unreactive in soil. In contrast, magnesium pyrophosphate quickly formed plant-available dimagnesium phosphate.Also the chemical form of phosphate phases in sewage sludge ash (SSA)-based fertilizers was determined by Raman microspectroscopy. Raman mapping with a lateral resolution of 5 × 5 μm(2) easily detected different compounds present in the fertilizers with the help of recorded reference spectra of pure substances. Phosphates with apatite structure and magnesium triphosphate were determined at around 960 and 980 cm(-1), respectively. Furthermore, calcium/magnesium pyrophosphates were detected in some samples. The review comprises the analysis of natural matrixes by IR, XRF or Raman and chemometrics. Potential applications of non-destructive spectroscopic techniques to achieve these principles are discussed in this review. Special emphasis is placed in environmental samples.
Regards,
Prem Baboo
Article Determination of Phosphorus Fertilizer Soil Reactions by Ram...
Article Determination of Phosphate Phases in Sewage Sludge Ash-Based...
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