PEDOT:PSS is a p type high conductivity polymer mixer semiconductor. It has applications in semiconductor devices where it functions as a hole transport layer in organic solar cells and hole injector in LEDs.
For more information please follow the paper:Article Solvent-induced changes in PEDOT: PSS films for organic elec...
and the paper:Article Modeling of organic semiconductor conduction parameters with...
Following the above researchers comments, there are several types of PEDOT:PSS solutions according to their conductivities. In general, PEDOT:PSS is a mixture of ionomers. According to their ratio of the mixture, the conductivity is different. Although the commercial products of PEDOT:PSS also have additional dopants to satisfy different purposes of the applications. For example, OLEDs, solar cells, anti-statics and capacitors.
There are more information that you could find in the following link