His first discovery (1923) was the intrinsic frequency \nu = mc²/h.
Then the Theorem of Harmony of Phases (1923) : an observer seeing the electron and its phase should see the same thing, so the product of the phase velocity and group velocity is c². Because of the Lorentz transform.
In consequence comes the wavelength of the phase, in the non-relativistic domain :
\lambda = h/(mv)
Where v is the group velocity.
Of course, an "observer" is supposed, say the frame of the laboratory, for instance.
Have you an experimental handle on the ion frame ?
Or only on the laboratory frame ?
It is well known that the relativistic muons coming from the high atmosphere from original cosmic rays, have for us terrestrial beings, life spans expanded by their apparent relativistic time. But we cannot attach a macroscopic clock to each incoming muon.
I don't say that the laws of special relativity are wrong, I just say that there is a local reference system around the earth. In which these laws are OK!
For the de Broglie wavelength λ, λ = h/mv, where h is the Planck constant; m is the invariant mass of the particle; and v is the velocity of this particle. (The equation can be rewritten as λ = h/p, because p = mv, where p is the momentum of the particle, for non-relativistic motion.)