Literature suggests the reaction of Zn salts with plant extract alone can yield ZnO NPs. Many of the literatures also mentions the addition of NaOH to the solution to maintain pH around 12 for formation of white precipitate resulting in NPs. I could not obtain ZnO NP unless I added NaOH solution. Reaction between Zn salts and NaOH can alone give ZnO NP. Then what is the role of plant extract if NaOH needs to be added?