Suppose I have made a deposition on a thin film of one material of a hexagonal structure and another different. How to know a mismatch of these two material structures?
For corrected answer need know what type of materials you is deposited. What thickness of deposited layers? If you deposited semiconductor materials method of X-ray diffraction is good method for mismatch structures. Another possibility for structures analysis is transmission microscopy. For more details answer I need have more information