I am sure that I got the solid solution of two different compounds of similar size but not able to fix two different functional groups in the same place.
Possibly they aren't at the same place. We cannot say anything without at least picture, or better, the data.
Thank you. I collected the data of this solid solution first and then I started solving the data like the way I do for single molecules. But the problem with the solid solution is I am able to fix either the nitro group/CF3 group but not able to do it together. At the same time I don't know whether I am solving it in a way for solid solution.
I am sorry to say that I am not aware of this disorder modeling or solid solution using partial occupation. I started like the normal refinement of this solid solution but there is one way to get the functional group either NO2 or CF3 groups. some tome the refinement wont give stable structure and it would fragment also. This is completely new so that I am trying to understand and learn.
Http://onlinelibrary.wiley.com/doi/10.1002/asia.201201162/abstract
A loud talk::
Is the compound paramagnetic ? If yes; try:
its ESR; first at RT and then at different low temperature/s. The splitting pattern (number of peaks), g and A values will be different if the two groups belong to two different compounds or they are present in the same compound.
Or
If diamagnetic:
try NMR. The number of peaks, J, k constants and chemical shifts values should differ largely in the two possibilities
Thank you sir. I am sure that this is organic compound and no unpaired electron distribution in this compound. So I think it is diamagnetic and I will try for NMR first for two individual compounds and one solid solution. I will update you the same. Thanks once again.
A point worth consideration:
If it is an organic compound, concentrate on J,k and δ values of (C-N) and (C-F) of the two individual compounds and the solid solution. C are the carbon nuclei directly bonded to N and F.
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