have you ever thought about fluortensides? Scotch 3M, for example, is a provider. Fluorosurfactants greatly reduce the surface tension of water. You may also need a mix of different surfactants and emulsifiers. SDS (Sodium Dodecly Sulfate) is also often used for emulsion polymerization. The suitable concentration of emulsifiers at which micelles form (critical micelle formation concentration) must be determined in the experiment.
Addressing a similar question we used a longer chain alcocol (butanol to octanol) as a solubility aiding agent. Try diluting with an alcohol, and the mix it with water. Will nit work on preparative scale, but may be the amount dissolved is enough for your experiments (?).