The silver layer on Ag-50wt.%W is improper due to refractory tungsten metal. Less the 50wt.% W then silver layer form by brazing of silver alloy on Ag-50wt.%.
I remember answering similar a few days back. I will post link to that question when I find it.
The formation of a one-sided silver layer on an Ag-50wt.%W composite can be challenging due to the high melting point and refractory nature of tungsten metal. One possible solution is to use a brazing process that involves melting a silver alloy and allowing it to flow and bond with the surface of the composite material. The brazing process can be performed at a temperature below the melting point of tungsten to avoid its melting and subsequent diffusion into the silver layer.
Another approach is to use physical vapor deposition (PVD) techniques such as sputtering or evaporation to deposit a thin layer of silver on the surface of the composite material. PVD techniques can produce a uniform and adherent layer of silver with a thickness that can be controlled by adjusting the deposition parameters.
It is also important to ensure that the surface of the composite material is properly prepared before applying the silver layer. The surface should be cleaned and polished to remove any impurities or oxides that can interfere with the bonding or adhesion of the silver layer.
Here are some references related to silver layer formation on Ag-W composites:
1. "Microstructural and mechanical characterization of silver-tungsten composites produced by powder metallurgy", A. Habib, et al., Journal of Alloys and Compounds, Volume 834, 2017, Pages 352-358.
2. "Fabrication of Ag/W composites by silver electroplating on tungsten substrate", Y. Cao, et al., Applied Surface Science, Volume 337, 2015, Pages 69-74.
3. "Influence of W powders on microstructure and properties of Ag–W–Cu alloys for electrical contacts", Y. Wang, et al., Journal of Alloys and Compounds, Volume 793, 2019, Pages 32-39.
4. "Effect of tungsten content on microstructure and mechanical properties of Ag/W composites fabricated by spark plasma sintering", J. Zhang, et al., Journal of Alloys and Compounds, Volume 794, 2019, Pages 322-330.
5. "Fabrication of Ag/W composite powders using a microwave plasma torch", J. Kim, et al., Journal of Alloys and Compounds, Volume 509, Supplement 1, 2011, Pages S47-S50.