If you have chemically synthesized GO or r GO solution, then by drop casting or dip-coating, you can get GO coated Au electrode. If you need thicker film then drop casting is better than dip coating. hope it will be helpful for you,
I vote for Idea #3 of Sai Siddhardha. It is very nice idea and the best in the lsit ! I would note however that if you have to conduct a transport experiment in this device, the Mercaptoarenes will build an additional barrier for injected charges above 100K, which have to be accounted. Still the chemical bonds are much better than any physi-sorption. You will just have to play a little bit with this technique. I will glad to send you (if you need) refs on accounting aforementioned molecular barrier