I was trying to calculate the j parameters for the double perovskite structure compound La2CoMnO6 the structure and the interaction pathways are shown in the figure below, to calculate the j parameters i have used the convention H = sum(i,j), and i have only considered the nearest neighbour contributions, the equations for ferromagnetic and different antiferromagnetic spin arrangements obtained are as follows (where C1-C7 are different configurations)

Efm = 8j3+4j4+4j5+8j6

Ec1 = -8j3-4j4+4j5+8j6

Ec2 = 8j3+4j4-4j5-8j6

Ec3 = -8j3+4j4-4j5+8j6

Ec4 = 8j3-4j4+4j5-8j6

Ec5 = -8j3+4j4+4j5-8j6

Ec6 = -8j3-4j4-4j5-8j6

Ec7 = 8j3-4j4-4j5+8j6

Questions

1- If I want to solve these equations by using substitution and elimination method then these are the possible ways

j3 = 1/32*(Efm+Ec2+Ec4+Ec7), similarly other combinations

j4 = 2*j3+[1/2*(Ec3+Ec5)] or j4 = 1/32*(Efm+Ec2+Ec3+Ec5) or j4 = -2*j3-(Ec1+Ec6), similarly other combinations

j5 = 1/16*(Ec1+Ec4+Ec5-Ec6) or j5 = 2*j3-[1/2(Ec2+Ec7)] or j5 = 1/16*(Ec2-Ec4-Ec5+EC6) or 1/32*(Efm-Ec2+Ec4-Ec7), similarly other combinations

j6 = after obtaining the values of j3,j4 and j5 they can be substituted in any one of the equations and j6 can be obtained or

j6 = 1/32*(Efm+Ec1-Ec2-Ec6)-1/2*Ec5 or j6 = 1/16*(Efm+Ec3)-1/2*Ec4 or j6 = -1/32*(Ec2+Ec4+Ec5+Ec6), similarly other combinations

We can see that there is no unique way to solve for the j in that case which equation is to be considered to obtain the value of j? in other words what is the ideal method to solve the equations?

More Abhijit Nayak's questions See All
Similar questions and discussions