X-ray does not really accumulate or cause any significant alteration in x-ray transmission. Primary mechanism of x-ray tube ageing is usually caused by outgazing and cathode degradation.
X-rays do not "accumulate" in the material of the X-ray tube.
The term "absorption" is used to describe decrease of intensity of X-ray beam when passing through any material object (including air and the walls of X-ray tube) as a result of a wide spectrum of interactions of the X-rays with matter. However X-rays do not activate the matter (in tot became radioactive thereafter). All the processes induced by passing X-rays (Rayleigh and Compton scattering, fluorescence, Auger electron emission) are immediately finished after the X-ray beam is off.
Also I do not thing the electron beam in X-ray tube can activate the anode material. This process happens at energy of electrons at least few orders of magnitude higher.
2. Adsorption of X-rays does not exist, so you don't need to worry about at all. All you can observe is absorption.
3. Lead - yes this metal is toxic and makes negative changes to your body if gets inside. But as long as it stays in the equipment it is safe. Thus:
- do not touch the lead elements; if you did - wash immediately your hands, especially before you eat something,
- do not manipulate lead shields /alter anything in the instrument unless you are really specialist in this (from the questions I see that's not the case),
- after you finish to use your equipment give it back for recycling, do not just throw out its elements - in this case toxic lead will be spread around and will became dangerous to you and other people.