You won't find the expected 1.5 eV bandgap of crystalline CZTS (sulfur) from those reflectance data. Unless very nice data, thin films will require additionnal transmittance data from which you will get the absorbance (A=1-R-T). The ideal being the spectral response (SR) of a working solar cell and then to plot it as: E.Ln²(1-SR) vs E, where E is the photon energy.