you can consider your condition as a time dependent in this case you have enable transient state or you can assume steady state and your thermal condition as a convection if you know the heat transfer coefficient and free stream temperature.
Typically we specify the whole domain, including the wall, the same temperature at time zero. If the wall has a thickness, then you specify the wall zone an initial temperature with an initial temperature. You can read my paper for a clue: Data 3D Time-Dependent Simulations of Onset of Transient Convecti...